TEXNIK O`SIMLIK MOYLARINI EPOKSIDLASH ORQALI POLIMERLAR UCHUN MODIFIKATORLAR OLISH
Keywords:
sunflower oil, epoxidation, formic acid, polyvinyl chloride, plasticizer, hydrogen peroxide, tetrabutyl titanate.Abstract
The interaction of sunflower oil and its derivatives with hydrogen peroxide in the presence of formic acid was studied. It has been shown that a mixture of dihydroxy and epoxy derivatives is formed in different proportions depending on the synthesis conditions. In studying the composition of epoxidized vegetable oils, molecular structure, dynamics of intermolecular interactions, chemical reaction mechanism were studied using modern analytical methods (YMR, NMR).
References
Rhee I. Evolution of environmentally acceptable hydraulic fluids / I. Rhee // NLGI Spokesman. - 1996. - № 60. - P. 28-31.
Padmasiri K. Gamage Epoxidation of some vegetable oils and their hydrolysed products with peroxyformic acid - optimised to industrial scale / K. Gamage Padmasiri // J. Natn. Sci. Foundation Sri Lanka. - 2009.Vol. 37, № 4. P. 229-240.