PRODUCTION OF INHIBITED ACID AND SYNERGIC INHIBITOR COMPOSITIONS BASED ON AMINOLYSIS PRODUCTS OBTAINED FROM POLYETHYLENE TEREPHTHALATE WASTES

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Abstract:

The article presents the technology for the preparation of inhibited acid and synergistic inhibitor compositions based on products obtained by aminolysis with triethanolamine (TEA) by recycling polyethylene terephthalate (PET) waste. Inhibited acid was formed by adding 20–25% mass hydrochloric acid to the aminolysis product obtained on the basis of PET:TEA. The level of corrosion protection of this inhibitor was evaluated on St.3 steel samples in various aggressive environments (NaCl, mineralized water, paraffin mixtures).  As a result, a protection level of 99.8–99.9% was determined at an inhibitor concentration of 10 g/l. The effectiveness of synergistic inhibitor compositions based on IXK–DEA–urea–formaldehyde–orthophosphoric acid in protecting against the accumulation of mineral salts was also studied. The results obtained confirm the temperature and environmental stability of the inhibitors, as well as the economic and environmental efficiency of PET waste recycling.

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How to Cite:

Мейлиева , Л. . (2025). PRODUCTION OF INHIBITED ACID AND SYNERGIC INHIBITOR COMPOSITIONS BASED ON AMINOLYSIS PRODUCTS OBTAINED FROM POLYETHYLENE TEREPHTHALATE WASTES. Eurasian Journal of Medical and Natural Sciences, 5(10), 112–121. Retrieved from https://in-academy.uz/index.php/EJMNS/article/view/61901

References:

Geyer, R., Jambeck, J. R., & Law, K. L. (2017). Production, use, and fate of all plastics ever made. Science Advances, 3(7), e1700782.

Meyliyeva L.Q., Davlyatova Z.M., Kadirov X.I. Polietilentereftalat asosli chiqindilarni qayta ishlash va olingan mahsulotlarning qo‘llanilish yangi sohalari. Farg‘ona politexnika instituti ilmiy – texnika jurnali. , Farg‘ona – 2022 , Tom 26, №2. 146-151 b.

Abdel-Hameed, R. H., El-Sayed, S. A., & Soliman, A. Y. (2020). Green recycling of poly(ethylene terephthalate) waste as corrosion inhibitor for steel in marine environment. Egyptian Journal of Chemistry, 63(9), 3441–3456.

L.M. Meyliyeva., V.Z. Nurmukhamedova., Sh.A. Niyozova., B.U. Zokirov., Sh.Sh. Khasanov., O.N. Ashirov., J.M. Abdurakhmanov., Sh.A. Mutalov. Investigation of the conditions of alcoholization of secondary polyethylene terephthalate with triethanolamine. European Chemical Bulletin. 2023, 12(4), 888-895 p.

Ghosal, K., Nayak, C., & Das, A. (2022). Recent advances in chemical recycling of polyethylene terephthalate: Methods and applications. Materials Advances, 3(4), 1721–1739.

Ahmed, M. A., Ibrahim, M. A. M., & El-Ghamry, H. A. (2024). Current and emerging trends of inorganic, organic and eco-friendly corrosion inhibitors: A review. RSC Advances, 14(8), 4215–4236.

A.T. Karimov., L.M. Meyliyeva., H.T. Tilovov., S.J. Kholikova., Kh.I. Kadyrov. Effective catalysts of the synthesis of quinoline and quinoline derivatives. European Chemical Bulletin. 2023, 12 (Regular Issue 6), 76-86 p.

L.M. Meyliyeva., Kh.I. Kadyrov. ML-IOMS-7 mineral tuzlar to‘planishiga qarshi ingibitorining ishlab chiqarish texnologiyasi va neft-gaz quduqlarida qo‘llanilishi. Central asian food engineering and technology. Xalqaro, elektron (online) jurnali volume 1, issue 2, september 2025 issn: 2181-385x. 69-76 b.

Răuță, D. I., Benea, L., & Păduraru, E. (2023). Recent development of corrosion inhibitors: Types, mechanisms and applications. Technologies, 11(3), 103.

Lin, H., Zhang, T., & Zhao, W. (2024). Corrosion inhibition properties and synergistic effects of novel organic inhibitors: A comprehensive review. Frontiers in Chemistry, 12, 11173720.

Tang, Z., Liu, J., & Zhang, X. (2025). Synergistic mechanism and corrosion inhibition effect of two structurally complex imidazole derivatives. Applied Surface Science, 669, 161205.

Abdel-Hameed, R. H., Fekry, A. M., & Shabana, A. A. (2023). Manufacturing of corrosion inhibitors and flow improvers from PET plastic waste. ACS Omega, 8(12), 10432–10442.

Abd El-Hameed, R. H., & Fekry, A. M. (2015). Aminolysis of polyethylene terephthalate waste as corrosion inhibitor for carbon steel in HCl corrosive medium. Journal of Industrial and Engineering Chemistry, 24, 314–321.

Tawfik, M. E. (2010). Aminolysis of poly(ethylene terephthalate) wastes based on sunlight and utilization of the end product. Journal of Applied Polymer Science, 118(1), 469–475.